IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Ethene with Amidosulfurous acid, diethyl-, methyl ester, (N-N diethyl sulfonamide, methylester)

Components:
   (1) Amidosulfurous acid, diethyl-, methyl ester, (N-N diethyl sulfonamide, methylester); C5H13NO2S; [21954-69-8]  NIST Chemistry WebBook for detail
   (2) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Makitra, R.G.; Moin, F.B.; Politanskaya, T.I.; Yas'kovyak, A.; Zh. Fiz. Khim. 1975, 49, 2723-2724; VINITI No. 1877-75.

Variables:
   Temperature = 253.15 K to 338.15 K
   Pressure = 13.3 to 96.7

Prepared By:
   W. Hayduk

Experimental Remarks:

   The solubility is expressed as 10⁴ x₁ where x₁ is the mole fraction.

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)


t/°C	T/K	Pressure [mm Hg]	Pressure [kPa]	Pressure Note	Mole Fraction (x₁)
−20	253.15	100	13.3	Partial P	5
−20	253.15	200	26.7	Partial P	7
−20	253.15	300	40.4	Partial P	10
−20	253.15	400	53.3	Partial P	12
−20	253.15	500	66.7	Partial P	15
−20	253.15	600	80.0	Partial P	20
−20	253.15	725	96.7	Partial P	25
−20	253.15	760 (1)	101.3	Partial P	19.4
−20	253.15	760 (2)	101.3	Partial P	25.97
0	273.15	100	13.3	Partial P	4
0	273.15	200	26.7	Partial P	6
0	273.15	300	40.4	Partial P	8
0	273.15	400	53.3	Partial P	11
0	273.15	500	66.7	Partial P	13
0	273.15	600	80.0	Partial P	17
0	273.15	725	96.7	Partial P	19
0	273.15	760 (1)	101.3	Partial P	18.9
0	273.15	760 (2)	101.3	Partial P	20.5
20	293.15	100	13.3	Partial P	2
20	293.15	200	26.7	Partial P	5
20	293.15	300	40.4	Partial P	6
20	293.15	400	53.3	Partial P	7
20	293.15	500	66.7	Partial P	8
20	293.15	600	80.0	Partial P	10
20	293.15	725	96.7	Partial P	12
20	293.15	760 (1)	101.3	Partial P	13.0
20	293.15	760 (2)	101.3	Partial P	12.7
35	308.15	100	13.3	Partial P	2
35	308.15	200	26.7	Partial P	4
35	308.15	300	40.4	Partial P	6
35	308.15	400	53.3	Partial P	7
35	308.15	500	66.7	Partial P	8
35	308.15	600	80.0	Partial P	8
35	308.15	725	96.7	Partial P	11
35	308.15	760 (1)	101.3	Partial P	11.9
35	308.15	760 (2)	101.3	Partial P	12.2
50	323.15	100	13.3	Partial P	1
50	323.15	200	26.7	Partial P	3
50	323.15	300	40.4	Partial P	5
50	323.15	400	53.3	Partial P	6
50	323.15	500	66.7	Partial P	7
50	323.15	600	80.0	Partial P	8
50	323.15	725	96.7	Partial P	10
50	323.15	760 (1)	101.3	Partial P	10.7
50	323.15	760 (2)	101.3	Partial P	10.3
65	338.15	100	13.3	Partial P	−
65	338.15	200	26.7	Partial P	1
65	338.15	300	40.4	Partial P	2
65	338.15	400	53.3	Partial P	3
65	338.15	500	66.7	Partial P	4
65	338.15	600	80.0	Partial P	6
65	338.15	725	96.7	Partial P	7
65	338.15	760 (1)	101.3	Partial P	8.1
65	338.15	760 (2)	101.3	Partial P	5.7

Notes:
   ¹  The solubility at 101.3 kPa was calculated by the compiler from Henry's constants given in the paper.
   ²  Solubility at 101.3 kPa as calculated by the compiler from H values listed below. The data were obtained from the paper deposited in VINITI, Moscow.

Method/Apparatus/Procedure:
   The method of measurement was not specified.
It is stated in the paper that Henry's law is obeyed. A check of the data shows that Henry's law is only very approximately obeyed.
Henry's constants, H in mm Hg/mole fraction, as determined by the authors and as calculated by the compiler are as follows:

                  (authors)      (compiler)
   t/°C         10^–2H         10^–2H
   –20         3920         2927
   0            4025         3714
   20              5830         6000
   35            6380         6222
   50            7090         ;   7407
   65               9350            13,333

Source and Purity of Materials:
   1. Ethene purity by gas chromatography was 99.5%.
   2. The solvent was washed and boiling temperature was measured at 4 mm mercury pressure as 115 °C. Actual purity not determined.

Estimated Errors:
   Solubility: δ x₁/x₁ = ± 0.1 or 10% (Compiler)