IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Ethene with Kerosenes; Gasoline
Components:
   (1) Kerosenes; Gasoline; ; []  NIST Chemistry WebBook for detail
   (2) Ethene, (Ethylene); C2H4; [74-85-1]  NIST Chemistry WebBook for detail
Original Measurements:
   Hannaert, H.; Haccuria, M.; Mathieu, M.P., Ind. Chim. Belge 1967, 32, 156-164.

 Variables:
   Temperature = 233.15 K to 293.15 K

 Prepared By:
   E.L. Boozer, H.L. Clever

 Experimental Remarks:
   The authors definitions are:

K = y1/x1 = mole fraction gas in gas phase ÷ mole fraction gas in liquid phase,

π/atm = total pressure,

ν = coefficient of fugacity.





 Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
   
T/KTemp NoteChemical NameHenry's law constant, K [atm1]Henry Constant NoteMole Fraction (x1)Enthalpy [kcal mol–1]Remark(s)
233.15 to 293.15Temp. Interval of MeasurementsKerosene A-144Kπυ at 293.15 K1 - 22.653.62 Constant A
233.15 to 293.15Temp. Interval of MeasurementsKerosene A-244Kπυ at 293.15 K1 - 22.414.42 Constant A
243.15 to 293.15Temp. Interval of MeasurementsKerosene A-348Kπυ at 293.15 K2 - 52.743.73 Constant A
243.15 to 293.15Temp. Interval of MeasurementsGasoline43Kπυ at 293.15 K1 - 32.423.435 Constant A
 Notes:
   1  log (Kπν/atm) = A – (ΔH/cal mol–1)/(2.3R(T/K))

 Method/Apparatus/Procedure:
   The authors describe three methods:
1.A. [Saturat. n°1]. A measure of the static pressure of saturation in an apparatus which gave a precision of 10 - 15 %.
1.B. [Saturat. n°2]. A measure of the static pressure of saturation in an apparatus which gave a precision of 2 - 5 %.
2. [Chromato]. A gas liquid chromatographic method estimated to have a precision of 2 - 5 %.
3. [Anal. directe]. Direct analysis of the gaseous and liquid phases.

Method 1.B. was used for all of the kerosene systems except kerosene A-6/A-5 between 243 and 293 K for which method 1.A. was used.

Source and Purity of Materials:
   (1) Ethene. Air Liquide. For narcosis, 99.9 per cent.
   (2) Kerosenes and gasoline.

   Distillation            Density               mol wt
   Range, t/°C               ρ20/g cm–3   
   A-1 150-280               0.7805               170
A-2 150-185               0.7700               145
A-3 207-255               0.784               192
Gasoline 94-168               0.7521               122

Estimated Errors:


References:
   The function, Kπυ/atm, is equivalent to a Henry's constant in the form H1, 2/atm = (f1/atm)/x1 where f1 is the fugacity.