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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Ethene with Benzene
Components:
(1) Ethene; C2H4; [74-85-1]
NIST Chemistry WebBook
for detail
(2) Benzene; C6H6; [71-43-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Jadot, R., J. Chim. Phys. 1972, 69, 1036-40.
Variables:
Temperature = 298.15 K
Pressure = 101.3 kPa
Prepared By:
C.L. Young
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
T/K
Pressure
Pressure Note
Henry's law constant, K [atm]
Enthalpy [/cal mol
1
(/J mol
)]
Enthalpy Note
298.15
0.01118
+ partial pressure of 101.3 kPa
89.46
625 (2615)
# ΔH∞
Notes:
#
Excess partial molar enthalpy of solution at infinite dilution.
+
Calculated by compiler assuming
x
C2H4
= 1/
H
.
Method/Apparatus/Procedure:
The conventional gas chromatographic technique was used. The carrier gas was helium. The value of Henry's law constant was calculated from the retention time. The value applies to very low partial pressures of gas and there may be a substantial difference from that measured at 1 atm. pressure. There is also considerable uncertainty in the value of Henry's constant since no allowance was made for surface adsorption.
Source and Purity of Materials:
No details given.
Estimated Errors:
Solubility: δ
H
= ± 2%
Temperature: δ
T
/K = ± 0.05