IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

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 Solubility System: Acenaphthene with Thiophene

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Components:
   (1) Thiophene; C4H4S; [110-02-1]  NIST Chemistry WebBook for detail
   (2) Acenaphthene; C12H10; [83-32-9]  NIST Chemistry WebBook for detail

Original Measurements:
   Choi, P.B.; McLaughlin, E., Ind. Eng. Chem. Fundam. 1983, 22, 46-51.

Variables:
   Temperature = Temperature

Prepared By:
   W. E. Acree, Jr.

Experimental Data:   (Notes on the Nomenclature)
  

T/K	Mole Fraction x1	Mole Fraction x2
307.3	0.2584	0.7416
319.6	0.3542	0.6458
328.4	0.4407	0.5593
355.7	0.5224	0.4776
344.8	0.6428	0.3572

Method/Apparatus/Procedure:
   Constant temperature bath and a precision thermometer. Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by noting the temperature at which the  last trace of solid solute disappeared.

Source and Purity of Materials:
   (1) 99.2 %, British Drug Houses, United Kingdom, was recrystallized and then zone refined.
   (2) Gold Label, 99.9+ %, Aldrich Chemical Company, was used as received.

Estimated Errors:
   Solubility: x₁: ± 0.0003.
   Temperature: T/K: precision ± 0.1.

References:
   ¹W.E. Acree, Jr.

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Last updated: February 18, 2015 (Created: August 17, 2007)