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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Naphthalene with 1-Butanol
Components:
(1) 1-Butanol; C4H10O; [71-36-3]
NIST Chemistry WebBook
for detail
(2) Naphthalene; C10H8; [91-20-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Sunier, A.A., J. Phys. Chem. 1930, 34, 2582-2597.
Variables:
Temperature = Temperature
Prepared By:
W.E. Acree, Jr.
Experimental Data:
(Notes on the Nomenclature)
T/K
Mole Fraction x
1
Mole Fraction x
2
307.9
0.0939
0.9061
320.8
0.1652
0.8348
331.0
0.2937
0.7063
341.6
0.6255
0.3745
Method/Apparatus/Procedure:
Constant temperature bath and a precision thermometer.
Mixtures of known concentrations were sealed in thick-walled glass tubes and placed in a constant temperature to equilibrate with gentle rotation to thoroughly mix contents. Bath temperature was slowly increased and solubility visually determined by noting the temperature at which the last trace of solid solute disappeared. Measurements repeated several times to verify results.
Source and Purity of Materials:
(1) Purity not specified, Eastman Kodak Company, Rochester, New York, USA, was recrystallized several times from methanol.
(2) Purity not given, Eastman Kodak Company, was distilled shortly before use.
Estimated Errors:
Temperature: T/K: precision ± 0.1. x
1
: ± 0.0002 (compiler).