IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Perylene with Benzene

Components:
   (1) Perylene; C20H12; [198-55-0]  NIST Chemistry WebBook for detail
   (2) Benzene; C6H6; [71-43-2]  NIST Chemistry WebBook for detail

Original Measurements:
   Mishra, D.S.; Yalkowsky, S.H., Ind. Eng. Chem. Res., 1990, 29, 2278-2283.

Variables:
   Temperature = 296 K

Prepared By:
   W.E. Acree, Jr.

Experimental Data:   (Notes on the Nomenclature)
  
t/°CMole Fraction x1Mole Fraction x2
23.00.03960.9604
Method/Apparatus/Procedure:
   Constant temperature bath, rotator, thermometer, and an uv/visible spectrophotometer.
Excess solute and solvent placed in screw-capped test tube and allowed to equilibrate for 3 days with gentle agitation in a constant temperature bath. Samples centrifuged for 30 minutes and concentrations were determined spectrophotometrically. Attainment of equilibrium verified by repetitive measurements 4 days later.

Source and Purity of Materials:
   (1) Reagent grade, source not specified, was used as received.
   (2) Reagent grade, source not specified, was used as received.

Estimated Errors:

   Temperature: T/K: ± 0.1 (compiler). x1: ± 5 % (relative error; compiler).