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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Perylene with Benzene
Components:
(1) Perylene; C20H12; [198-55-0]
NIST Chemistry WebBook
for detail
(2) Benzene; C6H6; [71-43-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Mishra, D.S.; Yalkowsky, S.H., Ind. Eng. Chem. Res., 1990, 29, 2278-2283.
Variables:
Temperature = 296 K
Prepared By:
W.E. Acree, Jr.
Experimental Data:
(Notes on the Nomenclature)
t/°C
Mole Fraction x
1
Mole Fraction x
2
23.0
0.0396
0.9604
Method/Apparatus/Procedure:
Constant temperature bath, rotator, thermometer, and an uv/visible spectrophotometer.
Excess solute and solvent placed in screw-capped test tube and allowed to equilibrate for 3 days with gentle agitation in a constant temperature bath. Samples centrifuged for 30 minutes and concentrations were determined spectrophotometrically. Attainment of equilibrium verified by repetitive measurements 4 days later.
Source and Purity of Materials:
(1) Reagent grade, source not specified, was used as received.
(2) Reagent grade, source not specified, was used as received.
Estimated Errors:
Temperature: T/K: ± 0.1 (compiler). x
1
: ± 5 % (relative error; compiler).