IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Thianthrene with Phenoxazine

Components:
   (1) Thianthrene; C12H8S2; [92-85-3]  NIST Chemistry WebBook for detail
   (2) Phenoxazine; C12H8NO; [135-67-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Cullinane, N.M.; Rees, W.T., Trans. Faraday Soc. 1940, 36, 506-514.

Variables:
   Temperature = Temperature

Prepared By:
   W.E. Acree, Jr.

Experimental Data:   (Notes on the Nomenclature)
  
T/KMole Fraction x1Mole Fraction x2
429.90.0001.000
428.10.0330.967
412.20.3410.659
393.40.4390.561
392.00.4580.542
399.40.5310.469
416.40.7490.251
427.50.9460.054
429.91.0000.000
Method/Apparatus/Procedure:
   Mixtures were placed in small capillary tubes. Temperature was slowly varied with ample time given for equilibration. Transition temperatures determined by visual observations. Reported temperatures verified by repetitive measurements.

Source and Purity of Materials:
   (1) Purity and chemical source were not specified in paper, was purified by sublimation and recrystallization from acetone.
   (2) Synthesized by authors, and was purified by recrystallization from alcohol and sublimation.

Estimated Errors:

   Temperature: T/K: ± precision 0.2 (compiler). x1: ± 0.002 (compiler).