IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Thioxanthene with Decahydronaphthalene
Components:
   (1) Thioxanthene; C13H10S; [261-31-4]  NIST Chemistry WebBook for detail
   (2) Decahydronaphthalene; C10H18; [91-17-8]  NIST Chemistry WebBook for detail
Original Measurements:
   Coon, J.E.; Auwaerter, J.E.; McLaughlin, E., Fluid Phase Equilibr. 1989, 44, 305-345.

 Variables:
   Temperature = Temperature

 Prepared By:
   W.E. Acree, Jr.

 Experimental Data:   (Notes on the Nomenclature)
  
T/KMole Fraction x1Mole Fraction x2
309.50.03520.9648
321.10.05440.9456
328.10.07030.9297
337.80.10290.8971
343.90.12790.8721
353.30.19100.8090
 Method/Apparatus/Procedure:
   Constant temperature bath and a precision thermometer.
Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by visual noting the same temperature at which the last trace of solid solute disappeared.

 Source and Purity of Materials:
   (1) 99+ %, gift from Dr. E. J. Eisenbraun, Oklahoma State University, USA, was recrystallized from toluene.
   (2) 99+ %, Aldrich Chemical Company, having isomer ratio of 60.6 % cis and 39.4 % trans, stored over molecular sieves.

 Estimated Errors:

   Temperature: T/K: ± precision 0.1. x1: ± 0.0003.