IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Water-d2 with Tetrachloromethane (carbon tetrachloride)
Components:
   (1) Water-d2; D2O; [7789-20-0]  NIST Chemistry WebBook for detail
   (2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Glasoe, P.K.; Schultz, S.D., J. Chem. Eng. Data 1972, 17, 66-8.

 Variables:
   Temperature = 288 K - 308 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol m**-3]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
155.7+/-0.10.713 x 10-25.47
257.5+/-0.20.949 x 10-27.28
308.4+/-0.31.07 x 10-28.21
3510.3+/-0.31.32 x 10-210.13
 Method/Apparatus/Procedure:
   The saturation of heavy water with tetrachloromethane was done in a closed system, protected from atmospheric moisture, and placed in a constant temperature water bath. The solubility of heavy water in tetrachloromethane was measured using the Karl Fischer titration method  with a "dead stop" end-point determination (ref. 1). 15 Trials were done at each temperature.

 Source and Purity of Materials:
   (1) Source not given, 99.8% pure, used as received.
   (2) Source not given. Reagent grade, purified by distillation before use.

 Estimated Errors:
   Solubility: See above.
   Temperature: ± 0.1 K (compiler).

 References:
   1 Wernimont, G.; Hopkinson, F. J. Ind. Eng.Chem. 1943, 12, 272.