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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Bromodichloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Bromodichloromethane; CHBrCl2; [75-27-4]
NIST Chemistry WebBook
for detail
Original Measurements:
McNally, M.E.; Grob, R.L., J. Chromatogr. 1983, 260, 23-32.
Variables:
Temperature = 303 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
6
* Mass Fraction w
1
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
30
3031.9
0.3023
3.333
Method/Apparatus/Procedure:
Standard solutions were prepared in 100 ml flasks. They were shaken for 5 minutes and then allowed to equilibrate in a constant temperature bath held at 30
o
C for 24 hours. Samples were pipetted in headspace vials, sealed, thermostated and then examined by the gas chromatographic head space analysis technique. An F. & M. Model 402 gas chromatograph equipped with dual columns and dual flame-ionization detectors was used.
Source and Purity of Materials:
(1) Chemical Service, West Chester, PA., purest grade available.
(2) Distilled and run through two Barnstead purification cartridges.
Estimated Errors:
Solubility: ± 150 ppm std. dev.
Temperature: ± 0.5 K (compiler).