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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Bromodichloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Bromodichloromethane; CHBrCl2; [75-27-4]
NIST Chemistry WebBook
for detail
Original Measurements:
Nicholson, B.C.; Maguire, B.P.; Bursill, D.B., Environ. Sci. Technol. 1984, 18, 518-21.
Variables:
Temperature = 293 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Henry's law constant [m**3 atm mol**-1]
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
20
1.6 x 10
-3
2.099
2.352
Method/Apparatus/Procedure:
The apparatus consisted of a stripping vessel similar to that described by Mackay et al. (ref. 1). The air entered through the top of the vessel and the diffuser was close to the bottom. The solution was added to the stripping vessel and the desired flow was maintained. Samples of the solution being stripped were taken for analysis. After extraction of the sample, the extracts were analyzed by a gas chromatograph equipped with a capillary column.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled and deionized.
Estimated Errors:
Solubility: ± 0.2 x 10
-3
std. dev.
Temperature: ± 0.1 K.
References:
1
Mackay, D.; Shiu, W. Y.; Sutherland, R. P. Environ. Sci. Technol. 1979, 13, 333.