IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Dibromochloromethane with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Dibromochloromethane; CHBr2Cl; [124-48-1]  NIST Chemistry WebBook for detail

Original Measurements:
   McNally, M.E.; Grob, R.L., J. Chromatogr. 1983, 260, 23-32.

   Temperature = 303 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°C106 * Mass Fraction w1102 * Mass Fraction w1 (compiler) 105 * Mole Fraction x1 (compiler)
   Standard solutions were prepared in 100 cm3 flasks. They were shaken for 5 minutes and then allowed to equilibrate in a constant temperature bath held at 30oC for 24 hours. Samples were pipetted into headspace vials, sealed,  thermostated, and then examined by the gas chromatographic head space analysis technique. An F. & M. Model 402 gas chromatograph equipped with dual columns and dual flame ionization detectors was used.

Source and Purity of Materials:
   (1) Chemical Service, West Chester, PA., USA., purest grade available used as received.
   (2) Distilled and run through two Barnstead purification cartridges.

Estimated Errors:
   Solubility: ± 36.4 ppm std. dev.
   Temperature: ± 0.5 K (compiler).