Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Dibromochloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Dibromochloromethane; CHBr2Cl; [124-48-1]
NIST Chemistry WebBook
for detail
Original Measurements:
McNally, M.E.; Grob, R.L., J. Chromatogr. 1984, 284, 105-16.
Variables:
Temperature = 303 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
g
1
/V
2
[g m**-3]
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
30
2509
0.2514
2.179
Method/Apparatus/Procedure:
Standard dibromochloromethane solutions of increasing concentration were prepared in volumetric flasks as described elsewhere (ref. 1). The aqueous organic liquid phase was 25 ml and the vapor phase above the mixture was 35 ml. The system was allowed to reach equilibrium in a constant temperature bath and then a sample was injected into the gas chromatograph. Values reported are an average of at least 5 measurements.
Source and Purity of Materials:
(1) Chemical Service, West Chester, PA., USA, purest grade available.
(2) Distilled and run through two Barnstead purification cartridges.
Estimated Errors:
Solubility: ± 3.47 % std. dev.
Temperature: ± 0.5 K (compiler).
References:
1
McNally, M. E.; Grob, R. L. J.Chromatogr. 1983, 260, 23.