The tribromomethane (1) and water
(2) binary system is discussed in two parts; part 1 is tribromomethane (1) in
water (2) and part 2 is water (2) in tribromomethane (1).
Part 1. All the available
data for the solubility of tribromomethane (1) in water (2) were considered
acceptable for use in the smoothing equation except the following reported values.
The datum of Squire and Caines (ref. 1) is rejected because of the lack of details
on the purity of the sample, method of the experimental work, and significant
deviation from other measurements. The approximate value of Booth and Everson
(ref. 2) is also rejected because it is significantly lower than later studies.
The datum of McNally and Grob (ref. 3) is rejected because the reported solubility
is rather higher than other determinations. The data of Wright et al. (ref.
4) are contrary to the general trend of the temperature dependence of the solubilities in water (formation of maximum) and are rejected.
The remaining data, mainly at 298 K, are in reasonable agreement although further studies are required before any values can be recommended without qualification.
The tentative solubility
values in mass per cent for tribromomethane (1) in water (2) over the 283 to 303 K temperature range were used to obtain the following equation:
Solubility [100 w1] = 2.371 0.01517 (T/K) + 2.7808 × 10-5 (T/K)2
This regression equation was established using
the combined data from (refs. 5 - 12), which yielded a standard deviation of
1.6 × 102.
The tentative solubility values in mass per cent at 5 K intervals for tribromomethane
(1) in water (2) are presented in the Table 1.
The curve obtained from the smoothing
equation is shown in Figure 1. It should be noted that the solubility minimum,
which is discussed in the Preface, appearing in the 283 to 303 K temperature
interval is not pronounced.
Part 2. The only datum available for the solubility of water (2) in tribromomethane (1) is that of Mackay et al. (ref. 9); therefore, no Critical Evaluation is possible. The interested reader is referred to the relevant Compilation Sheet for the experimental solubility.