IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichlorofluoromethane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichlorofluoromethane; CCl3F; [75-69-4]  NIST Chemistry WebBook for detail

Original Measurements:
   Wisegarver, D.P.; Cline, J.D., Deep-Sea Res. 1985, 32, 97-106.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)Bunsen's Coefficient
250.1582.080.246
Method/Apparatus/Procedure:
   The equilibration took place in a 2 liter flask rotating in a constant temperature bath for 20 hours. The analysis of CCl3F was carried out using a Hewlett-Packard 63Ni electron capture detector mounted in a gas chromatograph. Peak areas were quantified by  a HP 3388A integrator and compared to the detector response of a standard sample.

Source and Purity of Materials:
   (1) AIRCO, Inc., used as received.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 2.0 %.
   Temperature: ± 0.05 K.