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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichlorofluoromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Trichlorofluoromethane; CCl3F; [75-69-4]
NIST Chemistry WebBook
for detail
Original Measurements:
Wisegarver, D.P.; Cline, J.D., Deep-Sea Res. 1985, 32, 97-106.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
Bunsen's Coefficient
25
0.158
2.08
0.246
Method/Apparatus/Procedure:
The equilibration took place in a 2 liter flask rotating in a constant temperature bath for 20 hours. The analysis of CCl
3
F was carried out using a Hewlett-Packard
63
Ni electron capture detector mounted in a gas chromatograph. Peak areas were quantified by a HP 3388A integrator and compared to the detector response of a standard sample.
Source and Purity of Materials:
(1) AIRCO, Inc., used as received.
(2) Distilled.
Estimated Errors:
Solubility: ± 2.0 %.
Temperature: ± 0.05 K.