IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Trichloromethane (chloroform) with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloromethane (chloroform); CHCl3; [67-66-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Booth, H.S.; Everson, H.E., Ind. Eng. Chem. 1948, 40, 1491-3.

   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°C102 * V1/V2102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)
   Equilibrium was ensured through repeated shaking and centrifuging of the trichloromethane and water mixture in a stoppered Goetz tube and returning the mixture to a constant temperature water bath. The difference between the total amount of trichloromethane  which was added and the amount remaining in excess was taken as the amount of trichloromethane dissolved in the known volume of water.The determination of the excess amount of trichloromethane added is described by Hanslick (ref. 1).

Source and Purity of Materials:
   (1) Commercial reagent, C. P. grade, used as received.
   (2) Distilled.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1 K (compiler).

   1 Hanslick, R. S. Ph. D. Thesis, Columbia University, 1935.