IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichloromethane (chloroform) with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloromethane (chloroform); CHCl3; [67-66-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Zielinski, A.Z., Chem. Stosowana 1959, 3, 377-84.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CDensity ρ [kg m**-3]102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)
251.449.73 x 10-26.41
Method/Apparatus/Procedure:
   The concentration of water in trichloromethane was determined by the Karl Fischer titration method (ref. 1).

Source and Purity of Materials:
   (1) Distilled (compiler).
   (2) Gliwice Chemicals, pure grade reagent, used as received.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1 K (compiler).

References:
   1 Mitchell, J.; Smith, D. M. Aquametry: A Treatise on Methods for the Determination of Water, Wiley, New York, 1952, p. 73 and 260.