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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloromethane (chloroform) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Trichloromethane (chloroform); CHCl3; [67-66-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Desnoyer, M., Dosage de l'Eau dand les Solvants Organiques par Absorption Infra-Rouge et Mesure des Constantes Dielectriques, Centre D'Etudes Nucleaires de Saclay, Report No. 1254, Saclay, France, June 23, 1959.
Variables:
Temperature = 299 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
10
3
* Mole Fraction x
1
(compiler)
10
2
* w
1
/M
1
(compiler) [mol g**-1]
26
8.6 x 10
-2
5.67
4.77 x 10
-3
Method/Apparatus/Procedure:
The saturation of trichloromethane with water took place at room temperature under vigorous stirring. The concentration of water in the organic rich phase was determined by infrared spectrometry.
Source and Purity of Materials:
(1) Distilled.
(2) Source not given. Commercial reagent, washed and dried before use.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K (compiler).