IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichloromethane (chloroform) with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloromethane (chloroform); CHCl3; [67-66-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Lowe, H.J.; Hagler, K. in Gas Chromatography, Biology and Medicine, Poster, R., Ed., Churchill, London, 1969, p. 86-112.

Variables:
   Temperature = 310 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°COstwald coefficient, L /dimensionless102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)
373.910.7881.197
Method/Apparatus/Procedure:
   The direct sample injection method was used. The sample containing the equilibration mixture of trichloromethane and water was injected into a chromosorb column equipped with an ionization detector. The response areas were compared with the gas standards analyzed under  similar conditions.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled (compiler).

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 0.5 K (compiler).