IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Trichloromethane (chloroform) with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloromethane (chloroform); CHCl3; [67-66-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Svetlanov, E.B.; Velichko, S.M.; Levinskii, M.I.; Treger, Yu.A.; Flid, R.M., Russ. J. Phys. Chem. 1971, 45, 488-90.

 Variables:
   Temperature = 288 K - 333 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * g1/g2102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
154.820.4807.27
303.200.3194.83
452.050.2053.10
601.300.1301.96
 Method/Apparatus/Procedure:
   The dynamic method was used for the determination of the solubility. It consisted of the saturation of nitrogen with trichloromethane vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of water. After 2-3 hours the solution  became saturated and samples were taken periodically (ref. 1). The concentration of trichloromethane in water was determined by GLC. On average, 3-5 measurements were taken at each temperature.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled (compiler).

 Estimated Errors:
   Solubility: ± 15 %.
   Temperature: ± 0.05 K.

 References:
   1 Treger, Yu. A.; Flid, R. M.; Spektor, S. S. Russ. J. Phys. Chem. 1964, 38, 253.