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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichlorofluoromethane with Water
Components:
(1) Trichlorofluoromethane; CCl3F; [75-69-4]
NIST Chemistry WebBook
for detail
(2) Seawater; ; []
NIST Chemistry WebBook
for detail
Original Measurements:
Warner, M.J.; Weiss, R.F., Deep-Sea Res. 1985, 32, 1485-97.
Variables:
Temperature = 272 K - 313 K
Concentration = Concentration
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* c
1
P
-1
[mol dm**-3 atm**-1]
-0.77
2.8152
-0.77
2.7588
-0.52
2.7263
-0.52
2.6985
-0.45
2.7107
-0.43
2.7065
-0.37
2.7110
-0.37
2.7056
4.79
1.9706
4.79
1.9446
4.79
1.9601
4.79
1.9607
4.81
1.8770
4.82
1.9773
4.84
1.9318
9.19
1.5302
9.19
1.5293
9.19
1.5330
9.19
1.5372
9.19
1.5727
9.19
1.5404
20.43
0.8648
20.44
0.8868
20.44
0.8792
20.44
0.8749
20.44
0.8788
20.44
0.8780
29.53
0.6085
29.53
0.6031
29.55
1.6182
29.55
0.6042
29.55
0.6037
29.55
0.6020
39.90
0.4280
39.91
0.4301
39.93
0.4299
39.93
0.4357
39.93
0.4281
Method/Apparatus/Procedure:
Equilibration of a dilute mixture of trichlorofluoromethane gas with seawater occurred in an equilibration chamber at various temperatures. Both gas and liquid phase concentrations were measured by gas chromatography using a Shimadzu
63
Ni electron capture detector operating in a constant current mode.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Surface water collected at La Jolla. Salinity = 35.807 ± 0.006 x 10
-3
.
Estimated Errors:
Solubility: ± 1.5 %.
Temperature: ± 0.02 K.