Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloromethane (chloroform) with Cesium chloride and Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Cesium chloride; CsCl; [7647-17-8]
NIST Chemistry WebBook
for detail
(3) Trichloromethane (chloroform); CHCl3; [67-66-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Pavlovskaya, E. M.; Charykov, A.K.; Tikhomirov, V.I., J. Gen. Chem. USSR, 1977, 47, 2230-4.
Variables:
Temperature = 293 K
Concentration = Concentration
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol m**-3]
Concentration c
2
[mol dm**-3]
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
20
-
0.5
-
-
20
64.5
1.0
0.6828
1.221
20
58.5
1.5
0.5830
1.143
20
-
2.0
-
-
20
56.0
2.5
0.5081
1.237
20
52.5
3.0
0.4560
1.263
Method/Apparatus/Procedure:
Trichloromethane was introduced from a microburet into an aqueous solution of cesium chloride which contained octanoic acid as an indicator. The mixture was vigorously stirred. The pH of the solution at first remained constant right up to the appearance of a second phase, i. e., up to the saturation of the aqueous phase with trichloromethane, after which the pH began to rise. The solubility was calculated from the volume of the aqueous phase and the volume of trichloromethane used for the saturation.
Source and Purity of Materials:
(1) Source nad purity not given.
(2) Source and purity not given.
(3) Distilled (compiler).
Estimated Errors:
Solubility: ± 10 %.
Temperature: ± 0.5 K (compiler).