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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloromethane (chloroform) with Rubidium chloride and Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Rubidium chloride; RbCl; [7791-11-9]
NIST Chemistry WebBook
for detail
(3) Trichloromethane (chloroform); CHCl3; [67-66-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Pavlovskaya, E. M.; Charykov, A.K.; Tikhomirov, V.I., J. Gen. Chem. USSR, 1977, 47, 2230-4.
Variables:
Temperature = 293 K
Concentration = Concentration
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol m**-3]
Concentration c
2
[mol dm**-3]
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
20
-
0.5
-
-
20
58.5
1.0
0.6454
1.0920
20
-
1.5
-
-
20
46.0
2.0
0.4738
0.9049
20
43.5
2.5
0.4635
0.8751
20
39.7
3.0
0.3852
0.8449
Method/Apparatus/Procedure:
Trichloromethane was introduced from a microburet into an aqueous solution of rubidium chloride which contained octanoic acid as indicator. The mixture was vigorously stirred. The pH of the solution at first remained constant right up to the appearance of a second phase, i. e., up to the saturation of the aqueous phase with trichloromethane, after which the pH began to rise. The solubility was calculated from the volume of the aqueous phase and the volume of trichloromethane used for the saturation.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Source and purity not given.
(3) Distilled (compiler).
Estimated Errors:
Solubility: ± 10 %.
Temperature: ± 0.5 K (compiler).