Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Triiodomethane (iodoform) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Triiodomethane (iodoform); CHI3; [75-47-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Dehn, W.M., J. Am. Chem. Soc. 1917, 39, 1399-404.
Variables:
Temperature = 293 K - 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* g
1
/g
2
10
2
* Mass Fraction w
1
(compiler)
10
6
* Mole Fraction x
1
(compiler)
20-25
1.0 x 10
-1
1.0 x 10
-1
4.57
Method/Apparatus/Procedure:
Excess triiodomethane in 5 cm
3
water samples were enclosed in small vials which, when stoppered, were shaken until equilibria were established. The solutions were filtered into weighed crucibles and reweighed. After drying in vaccum desiccators, the crucibles were again weighed and the loss of water calculated. No great accuracy was claimed for the experiments.
Source and Purity of Materials:
(1) From reliable firms; "not always pure."
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 5 K.