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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Bromochloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Bromochloromethane; CH2BrCl; [74-97-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Tewari, Y.B.; Miller, M.M.; Wasik, S.P.; Martire, D.E., J. Chem. Eng. Data 1982, 27, 451-4.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol m**-3]
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
25.0
125
1.646
2.325
Method/Apparatus/Procedure:
The modified generator column method was used. A chromatographic column was coated with bromochloromethane. An aqueous phase was generated by pumping water through the coated generator column. The aqueous solution was analyzed by a gas chromatography. The gas chromatograph was equipped with a flame ionization detector. On average, at least three measurements were taken.
Source and Purity of Materials:
(1) Source not known, at least 99 % pure by GC analysis.
(2) Baker-analyzed HPLC grade.
Estimated Errors:
Solubility: ± 1.0 %.
Temperature: ± 0.1 K.