IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Bromochloromethane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Bromochloromethane; CH2BrCl; [74-97-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Tewari, Y.B.; Miller, M.M.; Wasik, S.P.; Martire, D.E., J. Chem. Eng. Data 1982, 27, 451-4.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol m**-3]102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)
25.01251.6462.325
Method/Apparatus/Procedure:
   The modified generator column method was used. A chromatographic column was coated with bromochloromethane. An aqueous phase was generated by pumping water through the coated generator column. The aqueous solution was analyzed by a gas chromatography. The  gas chromatograph was equipped with a flame ionization detector. On average, at least three measurements were taken.

Source and Purity of Materials:
   (1) Source not known, at least 99 % pure by GC analysis.
   (2) Baker-analyzed HPLC grade.

Estimated Errors:
   Solubility: ± 1.0 %.
   Temperature: ± 0.1 K.