IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Bromochloromethane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Bromochloromethane; CH2BrCl; [74-97-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Miller, M.M.; Wasik, S.P.; Huang, G.L.; Shiu, W.Y.; Mackay, D., Environ. Sci. Technol. 1985, 19, 522-529.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)n1/V2 [mol m**-3]
251.6462.325129.0
Method/Apparatus/Procedure:
   A saturated aqueous solution was prepared by passing water through a column which was packed with glass beads coated with bromochloromethane. The saturated solution was then pumped through an extractor column and bromochloromethane was extracted into an analytical  column. The samples were analyzed with a liquid chromatograph equipped with both an UV absorbance and a fluorescent detector with excitation filters. The peak area was established using a Hewlett-Packard integrator.

Source and Purity of Materials:
   (1) Eastman Kodak Co., Commercial quality, used as received.
   (2) Double distilled.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 1 K (compiler).