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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Bromochloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Bromochloromethane; CH2BrCl; [74-97-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Miller, M.M.; Wasik, S.P.; Huang, G.L.; Shiu, W.Y.; Mackay, D., Environ. Sci. Technol. 1985, 19, 522-529.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
n
1
/V
2
[mol m**-3]
25
1.646
2.325
129.0
Method/Apparatus/Procedure:
A saturated aqueous solution was prepared by passing water through a column which was packed with glass beads coated with bromochloromethane. The saturated solution was then pumped through an extractor column and bromochloromethane was extracted into an analytical column. The samples were analyzed with a liquid chromatograph equipped with both an UV absorbance and a fluorescent detector with excitation filters. The peak area was established using a Hewlett-Packard integrator.
Source and Purity of Materials:
(1) Eastman Kodak Co., Commercial quality, used as received.
(2) Double distilled.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 1 K (compiler).