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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Clifford, C.W., Ind. Eng. Chem. 1921, 13, 628-32.
Variables:
Temperature = 297 K - 302 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
10
4
* Mole Fraction x
1
(compiler)
10
2
* w
1
/M
1
(compiler) [mol g**-1]
24
1.0 x 10
-2
8.53
5.55 x 10
-4
28.5
1.3 x 10
-2
11.09
7.22 x 10
-4
Method/Apparatus/Procedure:
The calcium chloride method was used for the determination of water in the samples. The moisture was abstracted from the samples by air and absorbed in two calcium chloride tubes. The two tubes were weighted before and after desorption. For further details, see (ref. 1).
Source and Purity of Materials:
(1) Distilled (compiler).
(2) Technical grade, used after distilling over CaCl
2
.
Estimated Errors:
Solubility: about 1 mg.
Temperature: ± 0.5 K (compiler).
References:
1
Clifford, C. W. J. Ind. Eng. Chem. 1921,13, 628.