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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Dichloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Dichloromethane; CH2Cl2; [75-09-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Prosyanov, N.N.; Shalygin, V.A., Zel'venskii, Ya.D., Tr. Mosk. Khim.-Technol. Inst. 183 (1973).
Variables:
Temperature = 298 K - 373 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Distribution coefficient, D
L
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
25.1
3920
0.0693
1.471
50.0
2480
0.2696
5.731
70.0
1650
0.7419
15.83
90.0
1240
1.6652
35.79
96.0
1130
2.1071
45.45
100
1080
2.4173
52.27
Notes:
1
Gas-liquid system analysis parameter, from calibration measurements.
Method/Apparatus/Procedure:
The distribution coefficient was determined by distillation. An inert gas was used to take samples from the vapor phase at equilibrium. The concentration of dichloromethane in both liquid and vapor phases was determined by using
36
Cl labeled compound.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K (compiler).