Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Dichloromethane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Dichloromethane; CH2Cl2; [75-09-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Howe, G.B.; Mullins, M.E.; Rogers, T.N., AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Variables:
Temperature = 283 K - 303 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
6
* Mass Fraction w
1
10
2
* Mass Fraction w
1
(compiler)
10
3
* Mole Fraction x
1
(compiler)
10
11092
1.1092
2.3736
20
13508
1.3508
2.8961
30
11211
1.1211
2.3993
Method/Apparatus/Procedure:
250 cm
3
bottles were filled with distilled deionized water and sealed. Measured volumes of dichloromethane were injected into the bottles through each bottle septum using a microliter syringe. Dichloromethane was in excess of the anticipated solubility limit. The bottles were shaken for one hour with wrist-action shaker and allowed to equilibrate for about 3 weeks. Samples were than injected into a gas chromatograph equipped with a Carbopack column and a FID detector. The GL response was compared with the calibration plot.
Source and Purity of Materials:
(1) Probably a commercial reagent at least 99 % pure. Used as received.
(2) Distilled and deionized.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K (compiler).