IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Dichloromethane with Hydrogen chloride

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Hydrogen chloride; HCl; [7647-01-0]  NIST Chemistry WebBook for detail
   (3) Dichloromethane; CH2Cl2; [75-09-2]  NIST Chemistry WebBook for detail

Original Measurements:
   Svetlanov, E.B.; Velichko, S.M.; Levinskii, M.I.; Treger, Yu.A.; Flid, R.M., Russ. J. Phys. Chem. 1971, 45, 488-90.

   Temperature = 288 K - 333 K
   Concentration = HCl concentration

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°C103 * Mass Fraction w1102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)Comment(s)
1529.402.9406.733Solubility of CH2Cl2 in 10% HCl solution
t/°C103 * Mass Fraction w1102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)Comment(s)
3024.502.4505.909Solubility of CH2Cl2 in 20% HCl solution
   The dynamic method was used for the determination of the solubility. It consisted of the saturation of nitrogen with dichloromethane vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of solution. After 2-3 hours  the solution became saturated and samples were taken periodically (ref. 1). The concentration of dichloromethane in the solution was determined by GLC. On average, 3 - 5 measurements were taken at each temperature.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Source and purity not given.
   (3) Distilled (compiler).

Estimated Errors:
   Solubility: ± 15 %.
   Temperature: ± 0.05 K.

   1 Treger, Yu. A.; Flid, R. M.; Spektor, S. S. Russ. J. Phys. Chem. 1964, 38, 253.