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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Eberius, E., Wasserbestimmung mit Karl-Fischer-Losung (Verlag, GMBH, Weinheim, 1954), p. 67.
Variables:
Temperature = 293 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
10
3
* Mole Fraction x
1
(compiler)
10
6
* w
1
/M
1
(compiler) [mol g**-1]
20
.012+/- 0.003
1.02
6.66
Method/Apparatus/Procedure:
A 50 g tetrachloromethane sample was shaken with pure water in a 100 ml Erlenmeyer flask. The two phases were separated when equilibrium had been established. The organic phase was analyzed for water using the Karl Fischer titration method. Five determinations were performed.
Source and Purity of Materials:
(1) Distilled.
(2) Source and purity not given.
Estimated Errors:
Solubility: See above.
Temperature: Not specified.