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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Johnson, J.R.; Christian, S.D., Affsprung, H.E., J. Chem. Soc. A. 1966, 77-8.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol m**-3]
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
25
8.7
9.89 x 10
-3
8.44
Method/Apparatus/Procedure:
Samples of water and tetrachloromethane mixtures were equilibrated in a constant temperature waterbath. The solute isopiestic apparatus has been described elsewhere (ref. 1). The water solubilities were determined using a Beckman Model KF-3 Aquameter.
Source and Purity of Materials:
(1) Distilled (compiler).
(2) Source not given, reagent grade, distilled in an Oldershaw column before use.
Estimated Errors:
Solubility: ± 0.3 x 10
-3
.
Temperature: ± 0.1
o
C.
References:
1
Christisn, S. D.; Affsprung, H. E.; Johnson,J. R.; Worley, J. D. J. Chem. Educ. 1963, 40, 419.