IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Tetrachloromethane (carbon tetrachloride) with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Johnson, J.R. Self-Association and Hydration of Phenol in Several Organic Solvents, Ph. D. Thesis, Univ. of Oklahoma, Norman, Oklahoma, 1966.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CConcentration c1 [mol m**-3]Concentration c2 [mol dm**-3]102 * Mass Fraction w1 (compiler) 102 * Mass Fraction w2 (compiler)
255.18.77.8 x 10-29.89 x 10-3
Method/Apparatus/Procedure:
   The equilibrium between tetrachloromethane and water took place in a well-stirred water bath. The experimental samples were allowed to equilibrate for two or more days. Water analyses were made with a Beckman Aquameter using a Karl Fischer reagent. The  solubility of tetrachloromethane in water was measured by using a vapor pressure measuring device. Full details are available in the thesis.

Source and Purity of Materials:
   (1) Allied Chemical Corp., purified by distillation before use.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 4 %.
   Temperature: ± 0.1 K.