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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Johnson, J.R. Self-Association and Hydration of Phenol in Several Organic Solvents, Ph. D. Thesis, Univ. of Oklahoma, Norman, Oklahoma, 1966.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Concentration c
1
[mol m**-3]
Concentration c
2
[mol dm**-3]
10
2
* Mass Fraction w
1
(compiler)
10
2
* Mass Fraction w
2
(compiler)
25
5.1
8.7
7.8 x 10
-2
9.89 x 10
-3
Method/Apparatus/Procedure:
The equilibrium between tetrachloromethane and water took place in a well-stirred water bath. The experimental samples were allowed to equilibrate for two or more days. Water analyses were made with a Beckman Aquameter using a Karl Fischer reagent. The solubility of tetrachloromethane in water was measured by using a vapor pressure measuring device. Full details are available in the thesis.
Source and Purity of Materials:
(1) Allied Chemical Corp., purified by distillation before use.
(2) Distilled.
Estimated Errors:
Solubility: ± 4 %.
Temperature: ± 0.1 K.