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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Freed, V.H.; Chiou, C.T.; Schmedding, D.; Kohnert, R., Environ. Health Perspect. 1979, 30, 75-80.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
6
* Mass Fraction w
1
10
2
* Mass Fraction w
1
(compiler)
10
5
* Mole Fraction x
1
(compiler)
25
800
8.0 x 10
-2
9.38
Method/Apparatus/Procedure:
A known volume of water was mixed with tetrachloromethane in Erlenmeyer flasks. The flasks, with their contents magnetically stirred, were immersed in a water bath. Samples were removed for analyses at regular intervals. All samples were analyzed by gas- iquid chromatography using an electron capture detector. The reported solubility is the average of five consecutive samples with less than 5% variation.
Source and Purity of Materials:
(1) Source not given. Analytical standard grade, purity is greater than 95 %.
(2) Distilled and run through a resin column.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K.