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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloromethane (carbon tetrachloride) with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Aref'eva, R.P.; Korenman, I.M.; Gorokhov, A.A., USSR Patent 672 548, July 5, 1979, 3 pp. (CA. 91:113 256k).
Variables:
Temperature = 293 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
g
1
/V
2
[kg m**-3]
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
20
0.87 ± 0.03
8.72 x 10
-2
1.02
Method/Apparatus/Procedure:
Equal quantities of diphenylthiocarbazone were added to aqueous solutions with different amounts of tetrachloromethane in several flasks. The contents of the flasks were shaken for 5 minutes and left to stand for 1 hour. The mixtures were then filtered through a paper filter and then concentration measurements were made by spectrophotometry. The turning point on the graph of optical density versus tetrachloromethane concentration was taken as the measurement.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: See above.
Temperature: ± 1 K (compiler).