IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Tetrachloromethane (carbon tetrachloride) with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Munz, C.D., Ph. D. Thesis, Stanford University, Stanford, CA., 1985, 306 pp.

   Temperature = 283 K - 303 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°CDensity ρ [kg m**-3]Henry's law constant [(dimensionless)]102 * Mass Fraction w1 (compiler) 105 * Mole Fraction x1 (compiler)
100.810.6098.10 x 10-29.493
200.784.9807.84 x 10-29.188
300.7551.5307.55 x 10-28.848
   The multiple equilibrium technique with direct aqueous injection into a gas chromatograph was used to determine the dimensionless Henry's law constant. A known volume of liquid and gas was introduced into a syringe and allowed to equilibrate. The ratio of gas to liquid volume  was maintained constant. While vapor samples were injected direct into a gas chromatograph, the liquid samples were preconcentrated by liquid-liquid extraction before analysis. The experiments were carried out in duplicates.

Source and Purity of Materials:
   (1) Aldrich Chemicals Co., WI, > 99.5 % pure.
   (2) Distilled and deionized.

Estimated Errors:
   Solubility: ± 1.28 x 10-2 std. dev.
   Temperature: ± 0.5 K.