IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Tetrachloromethane (carbon tetrachloride) with Hydrogen chloride and Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Hydrogen chloride; HCl; [7647-01-0]  NIST Chemistry WebBook for detail
   (3) Tetrachloromethane (carbon tetrachloride); CCl4; [56-23-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Svetlanov, E.B.; Velichko, S.M.; Levinskii, M.I.; Treger, Yu.A.; Flid, R.M., Russ. J. Phys. Chem. 1971, 45, 488-90.

 Variables:
   Temperature = 288 K - 333 K
   Concentration = Concentration

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * Mass Fraction w1102 * Mass Fraction w1 (compiler) 102 * Mass Fraction w2105 * Mole Fraction x1 (compiler)
151.001.00 x 10-11012.35
30.555.5 x 10-2106.79
45.303.0 x 10-2103.70
60.181.8 x 10-2102.22
151.251.25 x 10-12016.31
30.747.4 x 10-2209.65
45.404.0 x 10-2205.21
60.232.3 x 10-2203.00
 Method/Apparatus/Procedure:
   The dynamic method was used for the determination of solubility. It involved the saturation of nitrogen with terachloromethane vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of the aqueous solution.  After 2 - 3 hours the solution became saturated and samples were taken periodically (ref. 1). The concentration of tetrachloromethane in the aqueous solution was determined by gas chromatography. On average 3 - 5 measurements were taken at each temperature.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Source and purity not given.
   (3) Distilled (compiler)

 Estimated Errors:
   Solubility: ± 15 %.
   Temperature: ± 0.05 K.

 References:
   1 Treger, Yu. A.; Flid, R. M.; Spector, S. S. Russ. J. Phys. Chem. 1964, 38, 253.