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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Carbon dioxide with Potassium nitrate and Water
Components:
(1) Potassium nitrate; KNO3; [7757-79-1]
NIST Chemistry WebBook
for detail
(2) Carbon dioxide; CO2; [124-38-9]
NIST Chemistry WebBook
for detail
(3) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Markham, A.A.; Kobe, K.A., J. Am. Chem. Soc. 1941, 63, 449-54.
Variables:
Temperature = 273.35 K to 313.15 K
Pressure = 273.35 K to 313.15 K
Concentration =
c
2
/mol kg
-1
= 0 - 3
Prepared By:
D.M. Mason
Experimental Remarks:
The authors fitted their data to equations:
S
m
/S
o
= am
2
+ 1/(1 + bm
2
), as follows:
t/°C a b
0.2 0.0350 0.170
25 0.0248 0.088
40 0.0343 0.086
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
t/°C
T/K
Keunen coefficient, S
S Note
α
α Note
Molality m
2
[mol/kg]
0.2
273.35
1.7025
b
1.7023
a
0.0
0.2
273.35
1.6740
b
1.6680
a
0.1
0.2
273.35
1.6584
b
1.6470
a
0.2
0.2
273.35
1.6012
b
1.5733
a
0.5
0.2
273.35
1.5142
b
1.4610
a
1
25
273.35
0.7587
b
0.7565
a
0.0
25
298.15
0.7552
b
0.7501
a
0.1
25
298.15
0.7500
b
0.7421
a
0.2
25
298.15
0.7345
b
0.7182
a
0.5
25
298.15
0.7156
b
0.6860
a
1
25
298.15
0.6834
b
0.6296
a
2
25
298.15
0.6568
b
0.5818
a
3
40
298.15
0.5173
b
0.5133
a
0.0
40
313.15
0.4937
b
0.4704
a
1
40
313.15
0.4776
b
0.4370
a
2
40
313.15
0.4642
b
0.4083
a
3
Notes:
a
α = Bunsen coefficient [cm
3
(STP) cm
-3
atm
-1
].
b
S
= Kuenen coefficient [cm
3
(STP) g
-1
(H
2
O) atm
-1
].
Method/Apparatus/Procedure:
The principle of the Ostwald method was used in which the gas is agitated with a measured quantity of gas-free liquid and the decrease in volume of solution-saturated gas is measured in a burette over mercury. The pressure was adjusted to yield one atmosphere partial pressure of carbon dioxide. The volume of gas was reduced to 0°C by the ideal gas law. Experiments were conducted to show that the agitation did not cause super-saturation.
Source and Purity of Materials:
(1) Commercial cylinder, 99.8 % pure.
(2) Analytical grade.
(3) Distilled and degassed..
Estimated Errors:
Solubility: δα/α, δS/S = ± 0.002 (authors).
Temperature: δ
T
/K = <± 0.1 at 0.2°C, ± 0.03 at other temperatures (authors)