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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Carbon dioxide with Water
Components:
(1) Carbon dioxide; CO2; [124-38-9]
NIST Chemistry WebBook
for detail
(2) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Austin, W.H.; Lacombe, E.; Rand, P.W.; Chatterjee, M., J. Appl. Physiol. 1963, 18, 301-4.
Variables:
Temperature = 293.2 K to 311.2 K
Prepared By:
C.L. Young
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
T/K
No.
StandardDeviation
Standard Deviation Note
Bunsen Mean
Bunsen Range
293.2
4
0.0015
a
0.8568
0.0037
297.2
3
0.0003
a
0.7641
0.0005
303.2
3
0.0015
a
0.6503
0.0039
308.2
5
0.0018
a
0.5825
0.0038
311.2
4
0.0014
a
0.5453
0.0021
Notes:
a
σ = Standard deviation.
Unit for α is cm
3
(STP) cm
-3
atm
-1
Method/Apparatus/Procedure:
Humidified gas dissolves in water. After equilibrium established 1 cm
3
sample withdrawn and analyzed with manometric Van Slyke apparatus. It was claimed that deionised, distilled water gave the same results as acidified water.
Source and Purity of Materials:
(1) Commercial sample, no othe details given.
(2) Distilled acidified with hydrochloric acid (0.01 mol dm
-3
).
Estimated Errors:
Temperature: δ
T
/K = ± 0.1.