IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ammonium dihydrogenphosphate with Water

Components:
   (1) Ammonium dihydrogenphosphate; NH4H2PO4; [7722-76-1]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Bergman, A.G.; Tashtemirov, R., Ukr. Khim. Zh. 1967, 33, 565.

Variables:

   Concentration = Temperature and composition.

Prepared By:
   J. Eysseltová

Experimental Data:   (Notes on the Nomenclature)
(Please see footnotes following the table(s).)
  
Solubility in the NH4H2PO4-H2O system.
t/°C102 * Mass Fraction w1m1 [mol/kg](a)Solid Phase(s)(b)
-2100.966A
-4171.78A
-4.5181.91A + B
-1.6192.04B
+2.5202.17B
+9.522.52.52B
+22.527.53.30B
+32.532.54.19B
+35.5344.48B + C
+39354.68C
+46.537.55.22C
+51.5405.80C
Notes:
   Table 1  a  The molalities were calculated by the compiler.
   Table 1  b  The solid phases are: A=ice; B=α-NH4H2PO4; C=β-NH4H2PO4.

Method/Apparatus/Procedure:
   A visual polythermic method was used. A mixture of solid carbon dioxide and acetone was used as the cooling agent.

Source and Purity of Materials:
   Reagent grade NH4H2PO4 was used. It had a melting point of 200 °C.

Estimated Errors:
   Solubility: No information is given.
   Temperature: No information is given.