IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ammonium dihydrogenphosphate with Diammonium hydrogenphosphate and Water

Components:
   (1) Ammonium dihydrogenphosphate; NH4H2PO4; [7722-76-1]  NIST Chemistry WebBook for detail
   (2) Diammonium hydrogenphosphate; (NH4)2HPO4; [7783-28-0]  NIST Chemistry WebBook for detail
   (3) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Akiyama, T.; Kanzaki, H.; Minagawa, S., Nippon Dojo Hiryogaku Zasshi 49, 243 (1978).

Variables:

   Concentration = Composition at 273 K, 298 K and 323 K.

Prepared By:
   Hiroshi Miyamoto

Experimental Data:   (Notes on the Nomenclature)
(Please see footnotes following the table(s).)
  
Solubility of NH4H2PO4 in water.
t/°C102 * Mass Fraction w1m1 [mol/kg](a)
019.22.07
2529.73.67
5040.65.94
Solubility of (NH4)2HPO4 in water.
t/°C102 * Mass Fraction w1m1 [mol/kg](a)
036.34.32
2541.65.39
5047.06.72
Notes:
   Table 2  a  These values were calculated by the compiler.

Method/Apparatus/Procedure:
   The NH4H2PO4 or (NH4)2HPO4 was added to water in a glass-stoppered bottle and heated on a water bath at 90 °C. The mixture was then allowed to settle at a given temperature for 7 days. Total nitrogen content in the saturated solutions was determined by chemical analysis. The phosphate content was determined as P2O5.

Source and Purity of Materials:
   Chemically pure ammonium salts were used.

Estimated Errors:
   Solubility: Nothing is specified.
   Temperature: Nothing is specified.