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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloroethene (trichloroethylene) with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Trichloroethene (trichloroethylene); C2HCl3; [79-01-6]
NIST Chemistry WebBook
for detail
Original Measurements:
Prosyanov, N.N.; Shalygin, V.A., Zel'venskii, Ya.D., Tr. Mosk. Khim.-Technol. Inst. 183 (1973).
Variables:
Temperature = 287 K - 373 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Distribution coefficient, D
L
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
14
1.196 x 10
4
3.469 x 10
-3
4.757 x 10
-2
21
9.42 x 10
3
6.217 x 10
-3
8.525 x 10
-2
32
6.75 x 10
3
1.440 x 10
-2
1.974 x 10
-1
50
4.36 x 10
3
4.696 x 10
-2
6.442 x 10
-1
60
3.06 x 10
3
9.74 x 10
-2
1.334 x 10
0
70.3
2.07 x 10
3
2.06 x 10
-1
2.836 x 10
0
80
1.45 x 10
3
4.05 x 10
-1
5.571 x 10
0
90.3
1.13 x 10
3
7.12 x 10
-1
9.825 x 10
0
96.6
1.08 x 10
3
8.95 x 10
-1
1.237 x 10
1
100
9.80 x 10
2
1.085 x 10
0
1.502 x 10
1
Notes:
a
Gas-liquid system analysis parameter, from calibration measurements.
Method/Apparatus/Procedure:
The distribution coefficient was determined by distillation. An inert carrier gas stream was used to take samples from the equilibrium vapor phase. The concentration of the trichloroethene in both liquid and vapor phases was determined by using
36
Cl labeled compound.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K (compiler).