IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichloroethene (trichloroethylene) with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloroethene (trichloroethylene); C2HCl3; [79-01-6]  NIST Chemistry WebBook for detail

Original Measurements:
   Prosyanov, N.N.; Shalygin, V.A., Zel'venskii, Ya.D., Tr. Mosk. Khim.-Technol. Inst. 183 (1973).

Variables:
   Temperature = 287 K - 373 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
141.196 x 1043.469 x 10-34.757 x 10-2
219.42 x 1036.217 x 10-38.525 x 10-2
326.75 x 1031.440 x 10-21.974 x 10-1
504.36 x 1034.696 x 10-26.442 x 10-1
603.06 x 1039.74 x 10-21.334 x 100
70.32.07 x 1032.06 x 10-12.836 x 100
801.45 x 1034.05 x 10-15.571 x 100
90.31.13 x 1037.12 x 10-19.825 x 100
96.61.08 x 1038.95 x 10-11.237 x 101
1009.80 x 1021.085 x 1001.502 x 101
Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

Method/Apparatus/Procedure:
   The distribution coefficient was determined by distillation. An inert carrier gas stream was used to take samples from the equilibrium vapor phase. The concentration of the trichloroethene in both liquid and vapor phases was determined by using  36Cl labeled compound.

Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled (compiler).

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 0.5 K (compiler).