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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Trichloroethene (trichloroethylene) with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Trichloroethene (trichloroethylene); C2HCl3; [79-01-6]
NIST Chemistry WebBook
for detail
Original Measurements:
Halliday, M.M.; MacDonald, I.; MacGregor, M.H.G., Br. J. Anaest. 49, 413 (1977).
Variables:
Temperature = 310 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Ostwald coefficient, L /dimensionless
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
36.85
1.64
0.141
1.94
Method/Apparatus/Procedure:
A constant flow of trichloroethene vapor was bubbled through water, allowing 45 minutes for equilibration. The concentration in the gas mixture was in the range 0.5-2 % (v/v) trichloroethene. A Riken 18A refractometer provided accurate estimations of gaseous concentrations of trichloroethene. Five samples of aqueous solutions were analyzed by gas chromatography. The chromatograph was equipped with a flame ionization detector and potentiometric recorder.
Source and Purity of Materials:
(1) ICI Pharmaceuticals, used as received.
(2) Distilled.
Estimated Errors:
Solubility: ± 0.02 SEM.
Temperature: ± 0.5 K (compiler).