IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Trichloroethene (trichloroethylene) with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Trichloroethene (trichloroethylene); C2HCl3; [79-01-6]  NIST Chemistry WebBook for detail

Original Measurements:
   Halliday, M.M.; MacDonald, I.; MacGregor, M.H.G., Br. J. Anaest. 49, 413 (1977).

Variables:
   Temperature = 310 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°COstwald coefficient, L /dimensionless102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
36.851.640.1411.94
Method/Apparatus/Procedure:
   A constant flow of trichloroethene vapor was bubbled through water, allowing 45 minutes for equilibration. The concentration in the gas mixture was in the range 0.5-2 % (v/v) trichloroethene. A Riken 18A refractometer provided accurate  estimations of gaseous concentrations of trichloroethene. Five samples of aqueous solutions were analyzed by gas chromatography. The chromatograph was equipped with a flame ionization detector and potentiometric recorder.

Source and Purity of Materials:
   (1) ICI Pharmaceuticals, used as received.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 0.02 SEM.
   Temperature: ± 0.5 K (compiler).