IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Trichloroethene (trichloroethylene) with Water.
Components:
   (1) Trichloroethene (trichloroethylene); C2HCl3; [79-01-6]  NIST Chemistry WebBook for detail
   (2) MQ-Water; ; []  NIST Chemistry WebBook for detail
Original Measurements:
   Munz, C.D., Ph. D. Thesis, Stanford University, Stanford, CA., 1985, 306 pp.

 Variables:
   Temperature = 293 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CHenry's law constant [(dimensionless)]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
200.4249.84 x 10-21.350
 Method/Apparatus/Procedure:
   The multiple equilibration technique with direct aqueous injection into a gas chromatograph was used to determine the dimensionless Henry's law constant. Known volumes of liquid and gas were introduced into a syringe and allowed to equilibrate.  The ratio of gas to liquid volume was maintained constant. While vapor samples were injected directly into a gas chromatograph, the liquid samples were preconcentrated by liquid-liquid extraction before analysis. The experiments were carried  out in duplicates.

 Source and Purity of Materials:
   (1) J. T. Baker Chemicals Co., N. J., greater than 99.5 % pure.
   (2) 0.25 mg total organic carbon/dm3; 0.75 mg COD/dm3.

 Estimated Errors:
   Solubility: ± 0.015 std. dev.
   Temperature: ± 0.5 K.