IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Pentachloroethane with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Pentachloroethane; C2HCl5; [76-01-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Hutchinson, T.C.; Hellebust, J.A.; Tam, D., et al. Hydrocarbons and Halogenated Hydrocarbons in the Aquatic Environment, Plenum Press, New York, 1980, p. 577-86.

Variables:
   Temperature = 298 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CDensity ρ [kg m**-3]102 * Mass Fraction w1 (compiler) 105 * Mole Fraction x1 (compiler)
250.4804.81 x 10-24.28
Method/Apparatus/Procedure:
   An excess quantity of pentachloroethane was added to water and stirred vigorously for 24 hours. After the sample was allowed to settle at 25 °C for 48 hours, the solution was extracted with cyclohexane. The samples were analyzed by an  Aminco-Bowman spectrophotofluorometer. A detailed description of the method has been reported elsewhere.1

Source and Purity of Materials:
   (1) Aldrich Chemicals, highest grade, used as received.
   (2) Double distilled.

Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 0.2 K (compiler).