IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: cis-1,2-Dichloroethene (cis-1,2-dichloro-ethylene) with Water.

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) cis-1,2-Dichloroethene (cis-1,2-dichloro-ethylene); C2H2Cl2; [156-59-2]  NIST Chemistry WebBook for detail

Original Measurements:
   Gossett, J.M., Environ. Sci. Technol. 1987, 21, 202-8.

Variables:
   Temperature = 283 K - 308 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°CHenry's law constant [m**3 atm mol**-1]CV102 * Mass Fraction w1 (compiler) 103 * Mole Fraction x1 (compiler)
10.31.72 x 10-33.590.76321.427
17.52.65 x 10-32.440.70371.315
24.84.08 x 10-36.320.63591.188
34.65.45 x 10-35.040.71861.343
Notes:
   a  CV = coefficient of variation ( = 100 S.D./mean).

Method/Apparatus/Procedure:
   A modification of the EPICS procedure was used for measuring Henry's law constants. A precise quantity of cis-1,2-dichloroethene was injected into serum bottles which contained distilled water. The bottles were incubated for 18-24 hours at four  desired temperatures in a reciprocating shaker bath. The headspace concentrations of the EPICS bottles were measured by a gas chromatograph which was equipped with a flame ionization detector. The mean of the coefficient of variation values was about 4.3%.

Source and Purity of Materials:
   (1) Aldrich Chemical Co., 97 % pure.
   (2) Distilled.

Estimated Errors:
   Solubility: See table above.
   Temperature: ± 0.1 K.