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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
trans-1,2-Dichloroethene (trans-1,2-dichloro-ethylene) with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) trans-1,2-Dichloroethene (trans-1,2-dichloro-ethylene); C2H2Cl2; [156-60-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Gossett, J.M., Environ. Sci. Technol. 1987, 21, 202-8.
Variables:
Temperature = 283 K - 308 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Henry's law constant [m**3 atm mol**-1]
CV
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
10.0
4.20 x 10
-3
1.76
0.5354
9.993
17.5
6.60 x 10
-3
2.27
0.4738
8.839
24.8
9.38 x 10
-3
2.07
0.4544
8.475
34.6
1.38 x 10
-2
1.75
0.4539
8.466
Notes:
a
CV = coefficient of variation ( = 100 S.D./mean).
Method/Apparatus/Procedure:
A modification of the EPICS procedure was used for measuring Henry's law constants. A precise quantity of trans-1,2-dichloroethene was injected into srum bottles which contained distilled water. The bottles were incubated for 18-24 hours at four desired temperatures in a reciprocating shaker bath. The headspace concentrations of the EPICS bottles were measured by a gas chromatograph which was equipped with a flame ionization detector. The mean of the coefficient of variation values was about 4.3%.
Source and Purity of Materials:
(1) Commercial grade, source not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: (2) Distilled
Temperature: ± 0.1 K (compiler).