IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1,2,2-Tetrachloroethane with Water.
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,1,2,2-Tetrachloroethane; C2H2Cl4; [79-34-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Prosyanov, N.N.; Shalygin, V.A., Zel'venskii, Ya.D., Tr. Mosk. Khim.-Technol. Inst. 183 (1973).

 Variables:
   Temperature = 287 K - 373 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CDistribution coefficient, DL102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
141.360 x 1031.95 x 10-32.094 x 10-2
328.80 x 1021.00 x 10-21.077 x 10-1
505.90 x 1024.20 x 10-24.509 x 10-1
605.50 x 1027.50 x 10-28.061 x 10-1
704.50 x 1021.47 x 10-11.579 x 100
804.40 x 1022.32 x 10-12.500 x 100
903.35 x 1024.57 x 10-14.926 x 100
90.42.95 x 1026.61 x 10-17.142 x 100
1002.80 x 1027.95 x 10-18.591 x 100
 Notes:
   a  Gas-liquid system analysis parameter, from calibration measurements.

 Method/Apparatus/Procedure:
   The distribution coefficient was determined by distillation. An inert carrier gas stream was used to take samples from the equilibrium vapor phase. The concentration of the 1,1,2,2-tetrachloroethane in both liquid and vapor phases was determined  by using a 36Cl labelled compound.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled (compiler).

 Estimated Errors:
   Solubility: Not specified.
   Temperature: ± 0.5 K (compiler).