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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Tetrachloroethene (tetrachloroethylene) with Water.
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Tetrachloroethene (tetrachloroethylene); C2Cl4; [127-18-4]
NIST Chemistry WebBook
for detail
Original Measurements:
Prosyanov, N.N.; Shalygin, V.A., Zel'venskii, Ya.D., Tr. Mosk. Khim.-Technol. Inst. 183 (1973).
Variables:
Temperature = 298 K - 373 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
Distribution coefficient, D
L
10
2
* Mass Fraction w
1
(compiler)
10
7
* Mole Fraction x
1
(compiler)
25
3.080 x 10
4
7.29 x 10
-4
7.92
50
1.090 x 10
4
6.91 x 10
-3
7.507 x 10
1
70
4.760 x 10
3
3.61 x 10
-2
3.9218 x 10
2
90
2.370 x 10
3
1.490 x 10
-1
1.6210 x 10
3
100
1.760 x 10
3
2.782 x 10
-1
3.0294 x 10
3
Notes:
a
Gas-liquid system analysis parameter, from calibration measurements.
Method/Apparatus/Procedure:
The distribution coefficient was determined by sample distillation in a stream of an inert carrier gas which was employed for the sampling of the equilibrium vapor phase. The concentration of the compound studied in both phases was determined through the use of a
36
Cl labeled compound.
Source and Purity of Materials:
(1) Source and purity not given.
(2) Distilled (compiler).
Estimated Errors:
Solubility: Not specified.
Temperature: ± 1 K (compiler).