IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,1,1-Trichloroethane with Water.

Components:
   (1) 1,1,1-Trichloroethane; C2H3Cl3; [71-55-6]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Schwarz, F.P.; Miller, J., Anal. Chem. 1980, 52(13), 2162-4.

Variables:
   Temperature = 283 K - 303 K

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Mass Fraction w1104 * Mole Fraction x1 (compiler)102 * w1/M1 (compiler) [mol g**-1]
10.00.180+/-0.0032.431.35 x 10-3
20.00.185+/-0.0012.501.39 x 10-3
30.00.159+/-0.0012.151.19 x 10-3
Method/Apparatus/Procedure:
   The aqueous solubility was determined by elution chromatography. The solute columns (3 mm o.d., 1.8 mm i.d.) were positioned vertically in a waterbath thermostat. The measurement time interval ranged from 1 day to 2 weeks. The average deviations  were calculated from several measurements on different samples. The elution chromatography method has been described elsewhere.1

Source and Purity of Materials:
   (1) Source not given. Commercial reagent, 98 wt. % pure, used as received.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 4 %.
   Temperature: ± 0.5 K.

References:
   1F. P. Schwarz, Anal. Chem, 52, 10 (1980).